Three Novel Thiazole-Arm Containing 1,3,4-Oxadiazole-Based [HS-HS] Fe(II) Dinuclear Complexes
نویسندگان
چکیده
Novel synthesis of 2,5-bis[(1,3-thiazol-2-ylmethyl)amino]methyl-1,3,4-oxadiazole (LThiazole) is reported, along with the preparation three new dinuclear Fe(II) complexes different counterions [FeII2(μ2-LThiazole)2](BF4)4·2CH3CN (1), [FeII2(μ2-LThiazole)2](ClO4)4 (2) and [FeII2(μ2-LThiazole)2](CF3SO3)4·2CH3CN (3). The obtained were characterized by single-crystal X-ray crystallography, SQUID magnetometry IR spectroscopy. structure crystalline material was determined at 120 K for 1 3. magnetic properties all (1–3) measured between 2–300 clearly show that stay in high-spin state over temperature range.
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ژورنال
عنوان ژورنال: Crystals
سال: 2022
ISSN: ['2073-4352']
DOI: https://doi.org/10.3390/cryst12030404